Starfire and Mr. Spock

Here's another pairing that I think would just write itself.  Their personalities could not be more different, and that would make for a lot of fun interaction as they faced various perils.  Spock was always my favorite Star Trek character as a kid, and still is.   I look forward to the next Star Trek film, and while Zachary Quinto does a great job as the new Spock, I hope that Leonard Nimoy can make another appearance as Spock Prime.